Beilstein J. Org. Chem.2012,8, 2176–2183, doi:10.3762/bjoc.8.245
, matrix-assisted laser desorption ionization mass spectrometry (MALDI-TOF MS), dynamic light scattering (DLS), gel-permeation chromatography (GPC) and turbidity measurements. Additionally, the viscosity change of the methacrylic homopolymer with RAMEB-CD was evaluated.
Keywords: (meth)acrylatedTriton
possible after the complexation of (meth)acrylatedTriton® X-100 (2 and 3) with RAMEB-CD (Scheme 3). The polymers 10 and 12 complexed with 1 equiv of RAMEB-CD precipitated during the polymerization, whereas the double complexed polymers 11 and 13 did not precipitate, as a consequence of the stronger host
hydrodynamic diameters and the transmittance support the described explanation for the viscosity curve on the rheometer.
Conclusion
It was possible to polymerize (meth)acrylatedTriton® as a stable complex with RAMEB-CD in water (10 to 13). Even after the polymerization, the complex with RAMEB-CD still existed
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Graphical Abstract
Figure 1:
Chemical structure of Triton® X-100 (1).